By Avraam I. Isayev
ISBN-10: 3527319298
ISBN-13: 9783527319299
A whole and well timed evaluation of the subject, this quantity of the encyclopedia imparts wisdom of primary ideas of polymer blends.
every one article is uniformly established for simple navigation, containing the newest learn & improvement and its uncomplicated rules and purposes.
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Additional info for Encyclopedia of Polymer Blends, Volume 1: Fundamentals
Example text
Typical system configurations are sketched schematically. Adapted from Reference [120]. 19 20 1 Molecular Simulation of Polymer Melts and Blends: Methods, Phase Behavior, Interfaces, and Surfaces for the interface potential between the interface and the surface to decay, they already begin to interact mutually. This indicates that our simulation cell is too small to accommodate two non-interacting solid–liquid and liquid–vapor interfaces. Nevertheless, we can reliably determine cVW cLW . In these limiting states, the container is either completely filled with vapor or liquid, and there are no liquid– vapor interfaces present.
It reflects the characteristic shear deformation of solute macromolecules, for example, for shear flows of star polymers [180] or DNA molecules [181]. Hydrodynamic flow also can be incorporated via a discretized version of the Boltzmann equation. This approach is known as the lattice Boltzmann (LB) method. The idea is to solve the linearized Boltzmann equation on an underlying lattice to propagate molecular populations (fictitious solvent particles), which define the density and velocity on each lattice site.
Temperatures clearly above the glass transition temperature. This effect has been demonstrated by variation of the cooling rate for coarse-grained models [221]. Therefore, one would expect that normally the glass transition temperature found in simulations is an overestimate (the absolute difference is largest for the so-called strong glassformers and weakest for the so-called fragile glassformers). In view of this fact, the good agreement between experimental results and simulations some times reported in the literature is somewhat surprising.
Encyclopedia of Polymer Blends, Volume 1: Fundamentals by Avraam I. Isayev
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